epimer in a sentence
Examples
- Formation of the S, S, S epimer is also avoided by keeping reaction temperature below-15 �C.
- Thus either epimer is converted into a near 1 : 1 mixture of both isomers upon full conversion of the substrate.
- Under mild basic conditions, this stereogenic center isomerizes; the S epimer is called "'neoamygdalin " '.
- This epimer was then converted to the "'35 "'by the simultaneous action of methanol and thiophenol.
- Mthanolysis of lactone 10 with NaOMe forms a mixture of hydroxyl ester 11 and its C-4a epimer ( Pancratistatin numbering ).
- While at Brown University, De Groot worked with Gabriel Meister and Bill Jesdale to develop the EpiMer and EpiMatrix epitope mapping tools.
- However, this possibility was excluded by the synthesis of the 11 epimer and the demonstration that it has different chromatographic behavior from ouabain.
- However, the undesired isomer can be recycled to the desired epimer in three steps, including Swern oxidation and Corey s asymmetric reduction.
- It is the ? epimer of zeranol ( ?-zearalanol ) and is a major metabolite of zeranol but with less biological activity.
- The alpha compound was therefore converted its epimer "'34 "'by first equilibrating in excess base followed by reacidifiying and diazomethane treatment.